I'm amazed howe people mix up the 3% and the 33%. I'll try again...
If the TOTAL amount of CO2 in circulation (the 'carbon cycle') is 100, then each year vast amount get both emitted and absorbed NATURALLY. However, there is, or was, pretty much a BALANCE between emission and absorbtion (there has to be! The amounts involved are so large that if sink or source stopped we'd either expire of CO2 poisoning or the CO2 vanish in years). Now, we are ADDING more CO2, a LOT more. Some of this the planet's CO2 sinks can absorb, but the sinks are clearly overwhealmed else the atmospheric conc of CO2 would not be changing. SO, CO2 rises in conc, now by 30 odd percent.
So, while of the CO2 IN THE CO2 CYCLE it's only a small amount, of the CO2 IN THE AIR it's a 33% increase.